Oral Presentation 24th Australian Conference on Microscopy and Microanalysis 2016

In situ applications of soft X-ray ptychography (#116)

Grant van Riessen 1 , Michael Jones 2 , Arie van Riessen 3 , Nicholas Phillips 1 , Martin de Jonge 2 , George Kourousias 4 , Alessandra Gianoncelli 4 , Benedetto Bozzini 5
  1. Department of Chemistry and Physics, La Trobe Institute for Molecular Sciences, La Trobe University, Melbourne, Victoria, Australia
  2. Australian Synchrotron, Clayton, Victoria, Australia
  3. John de Laeter Centre, Curtin University, Bentley, Western Australia, Australia
  4. Elettra Sincratrone, Trieste, Italy
  5. Dipartimento di Ingegneria dell’Innovazione, Università del Salento, Lecce, Italy

Coherent diffractive imaging (CDI) with synchrotron X-ray beams allows extended objects to be characterised at high spatial resolution (<30 nm) and high energy resolution (0.1 eV).   In an implementation of CDI known as ptychography, a far-field diffraction pattern is measured from many overlapping regions as the sample is scanned through a coherent X-ray beam. Quantitative images of an object are then obtained from the far-field intensity pattern through iterative reconstruction algorithms. This provides a unique method of studying the elemental and chemical-state distributions in relatively thick materials and their relationship to nanoscale morphology. The high coherent flux offered by synchrotron X-ray sources can also potentially allow high temporal resolution through the use of emerging detector technology and advanced image reconstruction algorithms. This in turn allows the nanoscale structure of functional materials to be studied under non-equilibrium real-time conditions. In this work, we review recent efforts to apply soft X-ray ptychography to in situ and operando applications at several synchrotron facilities.  We emphasise studies of functional materials that are characterised by heterogeneity over a range of relevant length scales, including energy storage materials based on polypyrrole nanocomposites and inorganic, aluminosilicate based ceramics.  Finally, a perspective on the future prospects of the method will be given, with particular attention to how experimental challenges can be overcome to achieve the spatiotemporal resolution limits defined by the available coherent flux from synchrotron light sources.